The Prins Reaction of Cyclooctene and Cyclododecene
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概要
- 論文の詳細を見る
The reaction products of the sulfuric acid-catalyzed condensation of cyclooctene or cyclododecene with formaldehyde in acetic acid at 40 °C were investigated. The reaction of cyclooctene gave a mixture of 4,5-hexa-methylene-1,3-dioxane, 2-cyclooctenylmethyl acetate, and 1-acetoxy-2-acetoxymethylcyclooctane, while reaction of cyclododecene gave a mixture of cyclic ethers; one was identified as 3-oxabicyclo[10,3,0]-6-pentadecene, and the others were estimated to be 15-acetoxy-3-oxabicyclo[9,3,1]pentadecane and 12,17-dioxatricyclo[13,3, 0,0<SUP>10,14</SUP>]-2-octadecene.
- 公益社団法人 日本化学会の論文
著者
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Uchida Akira
Department Of Biomolecular Science Faculty Of Sciece Toho University
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Matsuda Sumio
Department of Petroleum Chemistry, Faculty of Engineering, Osaka University
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Maeda Toyohiro
Department of Petroleum Chemistry, Faculty of Engineering, Osaka University
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