Mechanism of Hydrogenolysis. III. Thermal Hydrogen Exchange and Demethylation of Toluene-2-<I>d</I><SUB>1</SUB>, -3-<I>d</I><SUB>1</SUB>, and -4-<I>d</I><SUB>1</SUB>
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概要
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Rates of gas phase thermal hydrogen exchange and hydrogenolytic demethylation of toluene-2-<I>d</I><SUB>1</SUB>, -3-<I>d</I><SUB>1</SUB>, and -4-<I>d</I><SUB>1</SUB> are evaluated using flow apparatus at temperatures 675–750 °C in the presence of a large excess molecular hydrogen. Both the exchange and the demethylation obey three-halves order rate law indicating the chain mechanism carried by hydrogen atom, the former being found slightly faster than the latter. Rate parameters of the two reactions taking place concurrently are then correlated with the extended Hückel superdelocalizability values appropriate to methylcyclohexadienyl transient formation. Overall applicability of the dynamic index as a measure of reactivity of deuteriotoluenes toward hydrogen atom attack is taken as an additional support for the generally accepted chain mechanism whose rate-determining step consists of electroneutral hydrogen atom addition to aromatic nucleus.
- 公益社団法人 日本化学会の論文
著者
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Sato Yoshiki
Department Of Urban Management Kyoto University
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Amano Akira
Department of Applied Chemistry, Faculty of Engineering, Tohoku University
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Sato Yoshiki
Department of Applied Chemistry, Faculty of Engineering, Tohoku University
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