Effect of Solvent Viscosity on the Decomposition of 1,1,4,4-Tetraphenyl-2-tetrazene

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概要

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• The rate of decomposition of 1,1,4,4-tetraphenyl-2-tetrazene (TPT) was measured in the polyethylene glycol (PEG) thickened dimethylformamide (DMF) of varying viscosities. The observed rate constant for the decomposition of TPT decreases with the viscosity of the DMF/PEG solvent system. A compensating change was found in the enthalpy and entropy of activation. It was also found that the decomposition of TPT occurs by the scission of only one N–N single bond, and undergoes cage return in the solvent system by recombination of radicals.

著者

• Nakaya Tadao

  Department of Applied Chemistry, Faculty of Engineering, Kinki University

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