Syntheses and Properties of 2′-Aminobiphenyl-2-ol and Its Copper(II) Complexes

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概要

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• A new bidentate ligand, 2′-aminobiphenyl-2-ol(Habp), was synthesized. An examination of its behavior toward metal ions proved that, depending on the reaction conditions, the ligand gave mononuclear or polynuclear copper (II) complexes with seven-membered chelate rings. The complexes of the following compositions were thus characterized: Cu(abp)<SUB>2</SUB>, Cu(abp)<SUB>2</SUB>·H<SUB>2</SUB>O, Cu(abp)<SUB>2</SUB>·C<SUB>6</SUB>H<SUB>6</SUB>, Cu(abp)<SUB>2</SUB>·CH<SUB>3</SUB>COOC<SUB>2</SUB>H<SUB>5</SUB>, and Cu<SUB>5</SUB>(abp)<SUB>8</SUB>(OH)<SUB>2</SUB>·3H<SUB>2</SUB>O.

• 公益社団法人 日本化学会の論文

著者

• Mori Iwao

  Department of General Education, University of the Ryukyus

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