A Study on Electronic Spectra of Organic Compounds with S–Cl Group
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概要
- 論文の詳細を見る
MO calculations were carried out for CH<SUB>3</SUB>SCl, C<SUB>6</SUB>H<SUB>5</SUB>SCl, and related compounds with the S–Cl group by the CNDO/2 or the ASMO-SCF method. The absorption bands in the 300–400 nm region observed were assigned to the σ<SUB>S-Cl</SUB><SUP>*</SUP>←<I>n</I><SUB>S</SUB> transition in view of transition energy and oscillator strength. Such characteristic bands are attributed to the extraordinarily low energy level of the σ<SUB>S-Cl</SUB><SUP>*</SUP> orbital.
- 公益社団法人 日本化学会の論文
著者
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Yamabe Tokio
Department Of Molecular Engineering Graduate School Of Engineering Kyoto University
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Fukui Kenichi
Department Of Chemistry Graduate School Of Science The University Of Tokyo
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Nagata Shinichi
Department of Hydrocarbon Chemistry, Faculty of Engineering, Kyoto University
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Kikuzono Yasuo
Department of Hydrocarbon Chemistry, Faculty of Engineering, Kyoto University
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Yamabe Tokio
Department of Hydrocarbon Chemistry, Faculty of Engineering, Kyoto University
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Fukui Kenichi
Department of Hydrocarbon Chemistry, Faculty of Engineering, Kyoto University
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