NMR spectroscopic studies on the tautomerism in Schiff bases of tenuazonic acid analogs.
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概要
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A NMR spectroscopic study of <SUP>15</SUP>N-enriched Schiff bases of such tenuazonic acid analogs as 3-acetyltetramic acid, 3-acetyltetronic acid, and 3-acetylthiotetronic acid showed the predominance of ketamine forms in their tautomeric equilibria in CDCl<SUB>3</SUB>. The ratios of "external tautomers" between two different ketamine forms, as calculated from the <SUP>15</SUP>N–H signal intensities, were compared favorably with the ratios obtained from the ring methylene signals.
- 公益社団法人 日本化学会の論文
著者
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Tsujimoto Toshio
Faculty Of Engineering Osaka City University
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Yamaguchi Tatsuaki
Laboratory Of Organic Chemistry Chiba Institute Of Technology
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Yuki Hidetaka
Faculty of Pharmaceutical Science, Toho University
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Tsujimoto Toshio
Faculty of Pharmaceutical Sciences, Osaka University
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Saito Kimitoshi
Laboratory of Organic Chemistry, Chiba Institute of Technology
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Yuki Hidetaka
Faculty of Pharmaceutical Sciences, Osaka University
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Yamaguchi Tatsuaki
Laboratory of Chemistry, Chiba Institute of Technology
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