The participation of solvents in the reaction of alkenes with manganese(III) acetate.

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概要

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• 1-Hexene and 2-methyl-2-pentene were heated with manganese(III) acetate at 100 °C in two mixed solvents of glacial acetic acid and acetic anhydride and of propionic acid and propionic anhydride in a nitrogen flow. γ-Acyloxy carboxylic acids, γ-lactones and saturated and unsaturated carboxylic acids were obtained, these oxidative products being considered to be adducts of acetic and propionic acids. Additional investigations were carried out on a mutual reaction of the oxidant and the solvents and on the thermal analysis of manganese(III) acetate. The reaction was explained by a solvent-participating free-radical mechanism.

• 公益社団法人 日本化学会の論文

著者

• OKANO Masayoshi

  Faculty of Integrated Art and Sciences, Hiroshima University

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