Solvent effect on the Raman spectra of mercury(II) halides.
スポンサーリンク
概要
- 論文の詳細を見る
Raman spectra show that the Hg–X bond strengths in mercury (II) halides are remarkably weakened by the interaction with certain solvents. Relations between the degree of this weakening and (a) the Lewis basicity (Gutmann's donor number) of the solvent and (b) the ionic character of the Hg–X bond are pointed out, together with a simple explanation.
- 公益社団法人 日本化学会の論文
著者
-
Sone Kozo
Department Of Chemistry Faculty Of Science Josai University
-
Fukuda Yutaka
Department Of Chemistry Faculty Of Science Ochanomizu Univeity
-
Aritaki Makiko
Department of Chemistry, Faculty of Science, Ochanomizu University
-
Hiraoka Keiko
Department of Chemistry, Faculty of Science, Ochanomizu University
関連論文
- Survival-promoting effect of electrical stimulation on axotomized retinal ganglion cells
- Thermodynamic Activity of Liquid Zn-Cd Alloys Studied by EMF Method with Zirconia Solid Electrolyte
- Syntheses and Structure of New Dinuclear Palladium(II)Complexes with 1, 1, 2, 2-Tetraacetylethanate and β-Diketonate
- d-f Metal Ion Interaction through Fe-C≡N-Ln Bridge between Dicyanobis(1,10-phenanthroline)iron(II) Complex and LnCl_3
- Formation and Structure of Mixed Quaternary Chelates with Late-Lanthanide Metal Ions
- Alcohol Brine Freezing of Japanese Horse Mackerel (Trachurus japonicus) for Raw Consumption
- Structure and Enantio-Differentiating Behaviors of Nickel(II) Complexes with Chiral Schiff Base Ligands Derived from 1,1'-Binaphthyl-2,2'-diamine
- Agmatine Suppresses Mesangial Cell Proliferation by Modulating Polyamine Metabolism
- Hemispheric differences in color detection : a comparison of visual reaction times in human subjects
- Observation of the New κ^2C,O:κ^2C',O' Coordination Mode of 1,1,2,2-Tetraacetylethanato Ligand in a Dinuclear 1,1,1,5,5,5-Hexafluoroacetylacetonato Palladium(II) Complex
- Effect of Freezing Rate on the Denaturation of Myofibrillar Protein in Fish Muscle (特集 次世代の高品質凍結食品を目指す新技術)
- Alkyl-Substitution Effect of the Diamine on Coordination Geometry and Ligand-Field Strength of Nickel(II) Mixed-Ligand Complexes Containing N-Alkylethylenediamine, Acetylacetonate, and Nitrate Ligands
- Synthesis, Crystal Structure, and Chromotropic Properties of Mixed-Ligand Nickel(II) Complexes with 1,3-Diketonate and P-N Bidentate Ligands
- Syntheses, Structures, Spectroscopic Properties, and Thermal Behavior of Nickel(II) Mixed-Ligand Complexes with N, N, N', N'-Tetramethylethylenediamine, Benzoylacetonate, and a Halide Anion
- Synthesis of New Cationic Schiff Base Complexes of Copper(II) and Their Selective Binding with DNA
- Apoptotic death of beta cells induced by optic nerve transection in adult cat retinas
- Synthesis, Characterization and Spin-Crossover Behaviors of [Co(hydroxycarboxylato)(triphos)] Complexes
- Structures and Magnetic Properties of Dinuclear Copper(II) Complexes Containing a Bulky Diamine Ligand, 1,2-Dipiperidinoethane
- Different Magnetic Properties for Diastereomers of Alkoxide-bridged (β-Diketonato)ruthenium(III) Binuclear Complexes
- Substituent and Solvent Effects on Square-Planar-Tetrahedral Equilibria of Bis[4-(arylimino)pentan-2-onato]nickel(II) and Bis[1-aryl-3-(phenylimino)butan-1-onato]nickel(II) Complexes
- Copper(II) Mixed Ligand Complex with an N-Alkylated Diamine and a New β-Diketonate
- Theoretical Study on the Disproportionation Reaction of Nickel(II) Mixed-Ligand Complexes Containing N,N,N',N'-Tetramethylethylenediamine, Benzoylacetonate, and a Halide Anion
- Raman Spectra of Hydroxo Complexes of Tin (II) and Lead (II) in Strongly Alkaline Solutions, and of Antimony (III) Fluoride in Various Solvents
- Steric Crowding Effect of 1,3-Diketonates on the Structures and the Solution Behaviors of Nickel(II) Mixed-Ligand Complexes
- Solvatochromism and Structure of Acetylacetonatocoper(II) Complexes with N,N'-Dipropyl-,N,N,N',N'-Tetraproplyl-, and N,N- and N,N'-Diisopropylethylenediamines
- Anion-Sensing Electrodes Based on Nickel(II) Mixed Ligand Complexes
- Studies on mixed chelates. XIX. 5-coordinate nickel(II) complexes with N,N,N'N",N"-pentamethyldiethylenetriamine and .BETA.-diketonates.
- A Ruptured Basilar Tip Aneurysm Showing Repeated Perianeurysmal Edema after Endovascular Coil Embolization: Case Report
- Studies on mixed chelates. XIII. Formation and electronic spectra of 5-coordinated mixed copper(II) chelates containing N-alkylated ethylenediamine, acetylacetonate, and halide anions.
- On Liquefaction Caused by the Trituration of Pairs of Solid Compounds
- Preparation and thermal square planar-octahedral transformation of nickel(II) complexes containing 1,2-butanediamine or 3,3-dimethyl-1,2-butanediamine in solid phase.
- The Structures and Thermal Behaviors of Bivalent Metal Succinates in the Solid State
- Influences of the lanthanoid contraction on the thermal dehydration reactions of lanthanoid(III) malonate hydrates.
- Studies on mixed chelates. VI. Mixed copper(II) chelates with N,N,N',N'-tetraethylethylenediamine and various .BETA.-diketones.
- On the assignment of band II in the electronic spectrum of (Ni(H2O)6)2+.
- Studies on mixed chelates. VII. Mixed nickel(II) chelates containing N,N'- or N,N-dialkylethylenediamines and acetylacetone.
- Single crystal X-ray and optical studies on bis(1,5-diazacyclooctane)-copper(II) nitrate, a thermochromic copper(II) complex involving hydrogen bonds between the ligand and the counter ion.
- Studies on mixed chelates. XVI. Mixed copper(II) chelates with 1,2-dipiperidinoethane and .BETA.-diketonates.
- Studies on mixed chelates. XV. An ESR investigation of solvaochromic copper(II) complexes with various N-alkylated ethylenediamines and .BETA.-diketonates.
- On some mixed chelates of nickel(II) which are highly volatile,fusible,and soluble in nonpolar solvents.
- Studies on Mixed Chelates. I. Mixed Copper(II) Chelates with N,N,N′,N′-Tetramethylenediamine and a Bidentate Ligand
- (Acetylacetonato)(N,N,N',N'-tetramethylethylenediamine)copper(II) tetraphenylborate as a solvent basicity indicator.
- Solvent and Temperature Effects on the Electronic Spectra of Mixed Nickel(II) Chelates with N,N,N′,N′-Tetramethylethylenediamine and Acetylacetone
- Studies on mixed chelates. XII. Formation and electronic spectra of 5-coordinated mixed copper(II) chelates containing N-alkylated ethylenediamine, acetylacetonate, and pseudohalide anions.
- Solvent effect on the Raman spectra of mercury(II) halides.
- Synthesis and Thermochromic Properties of New Five-coordinate Copper Chelates
- Thermal dehydration reactions of bivalent transition metal malonate dihydrates in solid state.
- Studies on mixed chelates. XI. Syntheses and comparative study of a new series of mixed nickel(II) chelates with halide and pseudohalide ligands.
- Syntheses and thermal properties of some bivalent transition metal complexes with 1,4-diazabicyclo[2.2.2]octane.
- Effect of solvent on the electrochemical properties of chromotropic copper(II) mixed chelates.