A shock-tube investigation of ethylene-oxygen-argon mixtures. Chemi-ionization and apparent activation energy.
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概要
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The reaction of ethylene–oxygen mixtures highly diluted with argon was studied over the temperature range of 1400–1800 K behind reflected shock waves by monitoring the total ionization. A kinetic study of the chemi-ionization in the ethylene oxidation was undertaken. It was inferred that the mechanism of CHO<SUP>+</SUP> formation was dependent on the composition and the temperature, and that the rate-determining step for the chemi-ionization was C<SUB>2</SUB>H<SUB>3</SUB>+O<SUB>2</SUB>→C<SUB>2</SUB>H<SUB>3</SUB>O+O.
- 公益社団法人 日本化学会の論文
著者
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Suga Masao
Department of Chemistry, Faculty of Science, Ehime University
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Hidaka Yoshiaki
Department Of Chemistry Faculty Of Science Ehime University
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Nishi Tomofumi
Department of Chemistry, Faculty of Science, Ehime University
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