RhCl(PPh3)3-catalyzed coupling of diorganomercurials.

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概要

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• RhCl(PPh<SUB>3</SUB>)<SUB>3</SUB> has been proved to be an effective catalyst for the reaction of various diorganomercurials to give such coupling products as conjugated diyne, conjugated diene, biaryl, and alkane in good yields under mild conditions. A probable mechanism including the oxidative addition of organomercurials to a rhodium complex and the subsequent reaction of two oxidative-addition adducts to yield the product was presented.

• 公益社団法人 日本化学会の論文

著者

• Takagi Kentaro

  College Of Liberal Arts And Science Okayama University

• HAYAMA Naomi

  College of Liberal Arts and Science, Okayama University

• Sakakibara Yasumasa

  College of Liberal Arts and Science, Okayama University

• Oka Shinzaburo

  College of Liberal Arts and Science, Okayama University

• Okamoto Tadashi

  College of Liberal Arts and Science, Okayama University

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• RhCl(PPh3)3-catalyzed coupling of diorganomercurials.

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