The crystal and molecular structure of dichloro [N,N-dimethyl-.ALPHA.-methyl-o-(butylphenylphosphino)benzylamine] palladium(II).

スポンサーリンク

概要

• 論文の詳細を見る

• The crystal structure of dichloro[<I>N</I>, <I>N</I>-dimethyl-α-methyl-<I>o</I>-(butylphenylphosphino)benzylamine]palladium-(II) has been determined from Mo<I>K</I>α diffraction data. The space group is P2<SUB>1</SUB> with <I>Z</I>=2, <I>a</I>=9.255(2), <I>b</I>=14.372 (3), <I>c</I>=8.584(1) Å, and β=105.99(1)°. The final <I>R</I> became 0.034 by least-squares refinement. The Pd atom has a square planar coordination of N, P, and two Cl atoms, which is considerably distorted by the intramolecular atomic repulsions. The Pd–N distance, 2.134(4) Å, which is longer than those found so far, is accompanied by a short distance 2.285(1) Å of trans Pd–Cl. A plot of Pd–Cl distance versus trans Pd–N distance in several Pd complexes, in which the nitrogen atom is not π-acceptor, shows a linear relationship with the correlation factor of −0.28(4).

• 公益社団法人 日本化学会の論文

著者

• Tsuji Jiro

  Tokyo Institute of Technology

• Sasada Yoshio

  Tokyo Institute of Technology

• Yamamoto Keiji

  Tokyo Institute of Technology

• Takenaka Akio

  Tokyo Institute of Technology

関連論文

• PB169 MACRORING CONTRACTION METHODOLOGY : A NOVEL ROUTE TO STEROID A,B,C RINGS BY THE TRANSANNULAR DIELS-ALDER REACTION OF THE 14-MEMBERED (E,E,E)-TRIENE
• Cationic Palladium Complex-catalyzed Cyclization-Hydrosilylation of Alkadiynes and Enynes
• Development of β-keto ester and malonate chemistry : Palladium-catalyzed new reactions of their allylic esters
• A new synthetic method for methyl dihydrojasmonate from a butadiene telomer.
• A simple synthetic method for 2,15-hexadecanedione from a butadiene telomer.
• The crystal and molecular structure of dichloro [N,N-dimethyl-.ALPHA.-methyl-o-(butylphenylphosphino)benzylamine] palladium(II).

スポンサーリンク