A simple synthetic method for 2,15-hexadecanedione from a butadiene telomer.

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概要

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• The terminal double bond of 3,8-nonadienoate was oxidized to methyl ketone with a catalyst system of PdCl<SUB>2</SUB>/CuCl/O<SUB>2</SUB> and the internal double bond was reduced to give 8-oxononanoate, which was hydrolyzed to 8-oxononanoic acid. The Kolbe electrolysis of the acid produced 2,15-hexadecanedione in a high yield.

• 公益社団法人 日本化学会の論文

著者

• Tsuji Jiro

  Tokyo Institute of Technology

• Yamada Toshiro

  Tokyo Institute of Technology

• Kaito Mitsumasa

  Tokyo Institute of Technology

• Mandai Tadakatsu

  Tokyo Institute of Technology

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• A simple synthetic method for 2,15-hexadecanedione from a butadiene telomer.
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