Reactions of aromatic compounds in molten salts. I. Dimerization of aromatic amines in a molten mixture of AlCl3-NaCl-KCl.

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概要

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• Aromatic amines underwent dimerization in a molten salt consisting of a mixture of AlCl<SUB>3</SUB>–NaCl–KCl. The reaction is an oxidative cationic polymerization but, in contrast with the reactions of the ordinary aromatic compounds which gave the corresponding polyaryls, in the cases of aromatic amines the reaction was regiospecific and stopped at the stage of biaryl to yield benzidine derivatives.

• 公益社団法人 日本化学会の論文

著者

• Matsui Kohji

  Faculty of Engineering, Gunma University

• Imaizumi Hiroshi

  Faculty of Engineering, Gunma University

• Sekiguchi Shizen

  Faculty of Engineering, Gunma University

関連論文

• Preparation and reactions of di-1,3,5-triazinyl ethers. I. Preparation of di-1,3,5-triazinyl ethers.
• Reactions of aromatic compounds in molten salts. I. Dimerization of aromatic amines in a molten mixture of AlCl3-NaCl-KCl.
• Reactions of aromatic compounds in molten salts. II. The rearrangement of phenylhydrazine to give o-phenylenediamine in a molten mixture of AlCl3-NaCl-KCl.

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