Reactions of aromatic compounds in molten salts. II. The rearrangement of phenylhydrazine to give o-phenylenediamine in a molten mixture of AlCl3-NaCl-KCl.

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概要

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• Phenylhydrazine gave <I>o</I>-phenylenediamines as the major product upon heating in a molten mixture of AlCl<SUB>3</SUB>–NaCl–KCl. In the molten mixture, some aromatic compounds gave the corresponding aromatic amines in good yields in the presence of phenylhydrazine, suggesting that the method provides a novel direct process for the preparation of aromatic amines.

• 公益社団法人 日本化学会の論文

著者

• Hashida Yoji

  Faculty of Engineering, Gunma University

• Matsui Kohji

  Faculty of Engineering, Gunma University

• Imaizumi Hisao

  Faculty of Engineering, Gunma University

関連論文

• Preparation and reactions of di-1,3,5-triazinyl ethers. I. Preparation of di-1,3,5-triazinyl ethers.
• Reactions of aromatic compounds in molten salts. I. Dimerization of aromatic amines in a molten mixture of AlCl3-NaCl-KCl.
• Reactions of aromatic compounds in molten salts. II. The rearrangement of phenylhydrazine to give o-phenylenediamine in a molten mixture of AlCl3-NaCl-KCl.

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