Hydrogen-deuterium exchange reaction via .BETA.-sulfinyl carbanion. Neighboring sulfur participation in carbanion formation.
スポンサーリンク
概要
- 論文の詳細を見る
The rate of base-catalyzed H-D exchange reaction of substituted cyclopropanes and cyclohexanes containing sulfur atom at the β-position of reaction center was investigated. Neighboring sulfur participation in stabilization of the carbanion was suggested in the case of ethyl <I>trans</I>-2-(phenylthio)cyclopropanecarboxylate.
- 公益社団法人 日本化学会の論文
著者
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Kaji Aritsune
Department of Chemistry, Faculty of Science, Kyoto University
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Hayami Jun-ichi
Department of Chemistry, Faculty of Science, Kyoto University
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Koyanagi Tohru
Department of Chemistry, Faculty of Science, Kyoto University
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