Magnetic circular dichroism of the thulium and erbium ethyl sulfate nonahydrate crystals.
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概要
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The magnetic circular dichroism and absorption spectra of the thulium and erbium ethyl sulfate nonahydrate crystals have been measured at low temperatures, down to 18 K. The analyses are made for five absorption bands of Tm(C<SUB>2</SUB>H<SUB>5</SUB>SO<SUB>4</SUB>)<SUB>3</SUB>·9H<SUB>2</SUB>O; the bands from the ground state, <SUP>3</SUP>H<SUB>6</SUB>, to the excited states <SUP>3</SUP>F<SUB>3</SUB>, <SUP>3</SUP>F<SUB>2</SUB>, <SUP>1</SUP>G<SUB>4</SUB>,<SUP>1</SUP>D<SUB>2</SUB>, and <SUP>3</SUP>P<SUB>1</SUB> of Tm<SUP>3+</SUP>, and for four bands of Er(C<SUB>2</SUB>H<SUB>5</SUB>SO<SUB>4</SUB>)<SUB>3</SUB>·9H<SUB>2</SUB>O; the bands from the ground state, <SUP>4</SUP>I<SUB>15⁄2</SUB>, to the excited states <SUP>4</SUP>S<SUB>3⁄2</SUB>, <SUP>4</SUP>F<SUB>5⁄2</SUB>, <SUP>4</SUP>F<SUB>3⁄2</SUB>, and <SUP>2</SUP>G<SUB>9⁄2</SUB> of Er<SUP>3+</SUP>. With the aid of the information about energy levels already obtained, the g values of the crystal levels relevant to absorptions are derived from the Faraday parameters; these are in good agreement with those obtained by other methods.
- 公益社団法人 日本化学会の論文
著者
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Nagai Toshiyuki
Department Of Cardiology Hiratsuka City Hospital
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Nakaya Toshikazu
Department of Chemistry, Faculty of Science, Kobe University
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Kato Yoshifumi
Department of Chemistry, Faculty of Science, Kobe University
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