A Chlorine NQR Study of Trichlorides of Group V Elements
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概要
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The NQR frequency of <SUP>35</SUP>Cl has been observed in polycrystalline PCl<SUB>3</SUB>, POCl<SUB>3</SUB>, AsCl<SUB>3</SUB>, and SbCl<SUB>3</SUB> at 77°K and above. In all cases, the resonance frequency decreases at higher temperatures. The temperature coefficient of the resonance frequency is analyzed according to a modified Bayer-type treatment. A qualitative examination of the experimental results, including Robinson's results for BiCl<SUB>3</SUB> at 83 and 299°K, reveals that the strength of the intermolecular interactions in the solids of these trichlorides decreases in this order: BiCl<SUB>3</SUB>>SbCl<SUB>3</SUB>>AsCl<SUB>3</SUB>>PCl<SUB>3</SUB>. The resonance was found to "fade-out" at temperatures below the melting point for the solids of PCl<SUB>3</SUB> and POCl<SUB>3</SUB>, while the resonance was observed up to the melting point for the other compounds. The origin of this phenomenon is discussed.
- 公益社団法人 日本化学会の論文
著者
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Hashimoto Masao
Department Of Chemistry Faculty Of Science Kobe University
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Kato Yoshifumi
Department of Chemistry, Faculty of Science, Kobe University
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Morie Toshiaki
Department of Chemistry, Faculty of Science, Kobe University
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