The esterification of thujopsene with bismuth(III) sulfate in carboxylic acids.

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概要

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• The catalytic interaction of <I>cis</I>-(−) -thujopsene with a series of organic acids from acetic to octanoic in the presence of bismuth(III) sulfate afforded the corresponding esters in 20–34% yields, accompanied by skeletal rearrangement. The follow-up of the reaction, an investigation of the reaction conditions, and the effects of catalysts are described.

• 公益社団法人 日本化学会の論文

著者

• Ito Masaaki

  Chemistry Laboratory, Department of General Education, Higashi Nippon Gakuen University

• Abe Kazuo

  Chemistry Laboratory, Department of General Education, Higashi Nippon Gakuen University

関連論文

• Novel lactonization of .GAMMA.-cyclopropyl carboxylic acid via acid-catalyzed cleavage of cyclopropane ring.
• Oxidation of thujopsene with metal acetate in acetic acid.
• Structure of the rearrangement product of dihydromayurone with boron trifluoride in acetic acid-acetic anhydride at 50.DEG.C.
• The esterification of thujopsene with bismuth(III) sulfate in carboxylic acids.

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