The crystal and molecular structure of dichlorobis(2-pyridinethiolato)tin(IV).
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概要
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The crystal and molecular structures of dichlorobis(2-pyridinethiolato)tin(IV) have been determined by X-ray analysis. The crystal belongs to the triclinic system: <I>a</I>=8.340(8), <I>b</I>=12.456(7), <I>c</I>=7.178(3) Å, α=86.46(4), β=111.06(5), γ=99.18(6)°, space group P\bar1 with <I>Z</I>=2. The structure was determined by the heavy atom method and refined by the block-diagonal least-squares method (<I>R</I>=0.058). The complex is a distorted octahedral complex in which 2-pyridinethiolato ligands act as bidentate ligands, two four-membered (Sn, S, C, and N) chelate rings being present. Two Sn–Cl bonds are <I>cis</I>, two Sn–N bonds are <I>cis</I>, and two Sn–S bonds are <I>trans</I> configuration.
- 公益社団法人 日本化学会の論文
著者
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Ueda Hideo
Central Hospital Japanese National Railway Kyorin University Medical School
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Masaki Mitsuo
Polymer Research Laboratory, Ube Industries, Ltd.
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Matsunami Satoshi
Polymer Research Laboratory, Ube Industries, Ltd.
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