Magnetic susceptibility of the so-called zero-valent aluminium complex of 2,2'-bipyridine, [Al(bpy)3]0 1/2THF.

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概要

• 論文の詳細を見る

• The magnetic susceptibility of tris(2,2′-bipyridine)aluminium(0) was determined between 4.2 and 300 K. It can be explained by a radical ion model in which three 2,2′-bipyridine radical ions are coordinated to an aluminium-(III) ion. Antiferromagnetic interaction operates between the radical ions with the exchange integral <I>J</I>⁄<I>k</I>=−110–115 K.

• 公益社団法人 日本化学会の論文

著者

• Hara Ken-ichi

  Department of Chemistry, Faculty of Science, Nagoya University

• Inoue Motomichi

  Department of Chemistry and Department of Physics, Faculty of Science, Nagoya University

• Horiba Tatsuo

  Department of Chemistry, Faculty of Science, Nagoya University

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