Optical spectra of the picrate ion in micellar and polymer micellar systems. Comment on the solvation of anions.
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概要
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The optical spectra of the picrate ion in a micellar solution indicate that slightly below the CMC of CTAB surfactant the anion is relatively free and exists as an ion pair above the CMC. The hydrophobic aggregate of TMAC invariably gives free ion. The polymer micelle of quaternized poly(4-vinylpyridine) results in a tight ion pair.
- 公益社団法人 日本化学会の論文
著者
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Shinkai Seiji
Department Of Applied Chemistry Faculty Of Engineering Kyushu University
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MANABE Osamu
Department of Applied Chemistry, Faculty of Engineering, Nagasaki University
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Manabe Osamu
Department of Industrial Chemistry, Faculty of Engineering, Nagasaki University
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Ide Toyoko
Department of Industrial Chemistry, Faculty of Engineering, Nagasaki University
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