Synthesis and unusual properties of trimethylsilylmethyl, neopentyl, and related alkylthallium compounds.
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概要
- 論文の詳細を見る
Synthesis of some new trimethylsilylmethyl, neopentyl, and isobutylthallium compounds is described. Dialkykhallium halides containing these bulky alkyl substituents were found to be dimeric, in marked contrast to the polymeric dimethylthallium halide analogs. Trimethylsilylmethylthallium diisobutyrate possesses much higher stability than the methyl and ethylthallium analogs. These facts were discussed in terms of the steric bulk of the alkyl groups attached to thallium.
- 公益社団法人 日本化学会の論文
著者
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Kurosawa Hideo
Department Of Applied Chemistry Faculty Of Engineering Osaka University
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Konishi Toshifumi
Department Of Chemistry College Of Engineering Shibaura Institute Of Technology
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Okawara Rokuro
Department of Applied Chemistry Faculty of Engineering Osaka University
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Kurosawa Hideo
Department of Petroleum Chemistry, Osaka University
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Konishi Toshifumi
Department of Petroleum Chemistry, Osaka University
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Numata Shigeaki
Department of Petroleum Chemistry, Osaka University
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