Reversible binding of NO to Fe(II)edta.
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概要
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The equilibrium constants, enthalpy, and entropy of the reversible binding of nitrogen oxide to Fe(II)edta in an aqueous solution have been measured in the temperature range 38.5 to 70 °C. Experiments were carried out by absorbing NO under O<SUB>2</SUB> free conditions. The results show that, in the absorption of NO with Fe(II)edta solution, the value of Δ<I>H</I><SUP>°</SUP> is −15.8 kcal/mol and Δ<I>S</I><SUP>°</SUP> is −20.7 e.u.
- 公益社団法人 日本化学会の論文
著者
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Kamo Tomoichi
Hitachi Research Laboratory Hitachi Ltd.
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NAKAJIMA Fumito
Hitachi Research Laboratory, Hitachi Ltd.
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Hishinuma Yukio
Hitachi Research Laboratory, Hitachi Ltd.
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Kaji Ryuichi
Hitachi Research Laboratory, Hitachi Ltd.
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Akimoto Hidetoshi
Hitachi Research Laboratory, Hitachi Ltd.
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Mori Toshikatsu
Hitachi Research Laboratory, Hitachi Ltd.
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Arikawa Yoshijiro
Babcock-Hitachi Ltd.
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Nozawa Shigeru
Babcock-Hitachi Ltd.
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KAJI RYUICHI
Hitachi Research Laboratory
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HISHINUMA YUKIO
Hitachi Research Laboratory
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