The Oxidation of ( + )-<I>p</I>-Menth-3-ene with Selenium Dioxide

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概要

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• The oxidation of ( + )-<I>p</I>-menth-3-ene by selenium dioxide in a mixture of glacial acetic acid and acetic anhydride was examined with special attention paid to the position of the oxidative attack, i. e., the C<SUB>2<SUP>－</SUP></SUB> or C<SUB>5</SUB>-position of the hydrocarbon. Careful examination of the reaction product showed that this oxidation yielded only (±)-<I>p</I>-menth-3-en-5-yl acetate (major product), (±)-<I>p</I>-menth-3-en-5-ol and (±)-<I>p</I>-menth-3-en-5-one. Thus, this oxidant selectively attacks an active methylene group at the C<SUB>5</SUB>-position of <I>p</I>-menth-3-ene.

• 社団法人 日本化学会の論文

著者

• Sugimoto Masako

  Department Of Health Chemistry Faculty Of Pharmaceutical Sciences Kyoto University

• Suga T.

  Department Of Dermatology Kagoshima University Faculty Of Medicine

• Suga Takayuki

  Department of Chemistry Faculty of Science Hiroshima University

• Matsuura Tamon

  Department of Chemistry Faculty of Science Hiroshima University

• Sugimoto Masako

  Department of Chemistry Faculty of Science Hiroshima University

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