Studies on Modified Hydrogenation Catalyst. I. Selective Hydrogenation Activity of Modified Raney Nickel Catalyst for Carbonyl Group and C=C Double Bond
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概要
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Hydrogenation activity of the Raney nickel catalyst for carbonyl compounds was greatly diminished, when the catalyst was treated with a solution of amino acid. On the other hand, no appreciable change in its hydrogenation activity for C=C double bonds occurred upon this treatment. When mesityl oxide was used as a substrate, selective hydrogenation was most clearly demonstrated.<BR>The effect of conditions of modification, such as concentration of the modifying solution, immersion time and kind of modifying reagent on the activity of the modified catalyst, were investigated.
- 社団法人 日本化学会の論文
著者
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Fukawa Hideaki
Division of Organic Chemistry Institute for Protein Research Osaka University
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Akabori Shiro
Division of Organic Chemistry Institute for Protein Research Osaka University
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Fukawa H.
Division of Organic Chemistry Institute for Protein Research Osaka University
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Izumi Yoshiharu
Division of Organic Chemistry Institute for Protein Research Osaka University
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Komatsu Shinichiro
Division of Organic Chemistry Institute for Protein Research Osaka University
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