The Crystal Structure of Nickel Dialpha-amino Isobutyrate Tetrahydrate

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概要

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• The unit cell of nickel(II) dialpha-amino isobutyrate tetrahydrate has the follwing dimensions; a=9.92, b=14.24, c=11.42Å, β=107.5°, and contains four chemical units. The space group is determined to be P2<SUB>1</SUB>/a.<BR>Buerger's minimum-function method was applied to the structure analysis, and the newly designed image-seeker was used. Two of the four water molecules are coordinated to the nickel ion, forming a distorted octahedron with the carboxylic oxygen and the amino nitrogen atoms. The other two water molecules play the role of binders for these octahedrons. The chelation of the amino acid molecules is of the cis-form. The structure of the skeleton of α-amino propionic acid in this complex is not planar, in contrast to that of its free acid.

• 社団法人 日本化学会の論文

著者

• NOGUCHI T.

  Department of Periodontology, School of Dentistry, Aichi-Gakuin University

• Noguchi Teruo

  Department of Physics Faculty of Science Osaka University

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