Studies on Heavy-Nitrogen Labeled Compounds. III. Preparation of <SUP>15</SUP>N-Labeled α-Hydroximinopropionic Acid
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概要
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By use of K<SUP>15</SUP>NO<SUB>3</SUB> as a starting material, α-hydroximinopropionic acid-<SUP>15</SUP>N was synthesized in accordance with the following reactions:<BR>K<SUP>15</SUP>NO<SUB>3</SUB>→K<SUP>15</SUP>NO<SUB>2</SUB>→<SUP>15</SUP>NH<SUB>2</SUB>OH→CH<SUB>3</SUB>C(=<SUP>15</SUP>NOH)COOH<BR>The above reactions were carried out without separating any intermediate products. The yield of α-hydroximinopropionic acid-<SUP>15</SUP>N was about 61% on the basis of K<SUP>15</SUP>NO<SUB>3</SUB>.
- 社団法人 日本化学会の論文
著者
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Sugimoto Norio
Osaka Research Laboratory Tanabe Seiyaku Co., Ltd.
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Meshi Teruhiko
Osaka Research Laboratory Tanabe Seiyaku Co., Ltd.
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Sato Y.
Osaka Research Laboratory Tanabe Seiyaku Co., Ltd.
関連論文
- Studies on Heavy-Nitrogen Labeled Compounds. III. Preparation of 15N-Labeled α-Hydroximinopropionic Acid
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