酸化還元樹脂に関する研究 : (第1報) -SH系酸化還元樹脂について

概要

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The thiol compounds, thiophenol-formalin, oxythiophenol-formalin, aminothiophenol-formalin, and thioglycolic acid anilid-formalin resins were synthesized, and their redox potentials and redox capacities were measured. As these compouds were newly synthesized ones their structures were presumed from the analysis of S or N. They are as follow, thiophenol-formalin-resin _??_ oxythiophenol-formalin-resin aminothiophenol-formalin-resin thioglycolic acid, anilid-formalin-resin thioglycolic acid 1 mol. /anilin 2 mol. The redox reactions of them proceeded slower, redoxpot entials were higher than those of the starting materials (monomer). In this report it is concluded that those -SH containing compounds may be appreciated as redox resins, and the application of them to the practical use will be expected.
社団法人日本農芸化学会の論文