飽和脂肪酸および芳香族酸のパラオキシフェナシルエステル

概要

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p-Hydroxyphenacyl esters of fatty acids were prepared as derivatives for separation and identification of fatty acids. p-Hydroxyphenacyl bromide used for their preparation was synthesized according to King-Ostrum's method, which involves selective bromination of ketones with copper (II) bromide. The p-hydroxyphenacyl esters of C2C20 saturated fatty acids and aromatic acids were obtained as colorless needles using p-hydroxyphenacyl bromide. It was found that the p-hydroxyphenacyl bromide serves as a useful reagent for the identification of saturated fatty acids and some aromatic acids. Properties of p-hydroxyphenacyl esters have also been investigated.
社団法人日本分析化学会の論文