ホスト-ゲスト化学の研究 : 分子認識の基礎と応用および新しい有機固体化学への展開

概要

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Some acyclic rigid compounds which bearing phenyl and hydroxyl groups were found to be good host compound. On the basis of this finding, we designed several new host compounds. Some optically active hosts were also designed. These hosts form crystalline inclusion compounds with a wide variety of guest compounds in which efficient and precise molecular recognition are observed.<BR>Application of the molecular recognition to isolation of compound in pure state from a mixture, isolation of water soluble material from aqueous solution, and isolation of natural product were studied. Optically active host includes one enantiomer selectively. By using the enantioselctive inclusion, optical resolution of some racemic guests were achieved efficiently.
社団法人有機合成化学協会の論文