オリゴ糖をKey出発物質とする生理活性物質の合成 : Ferrier反応との組み合わせを中心に

概要

論文の詳細を見る
The readily available di- and tri-saccharides such as maltose and maltotriose were employed as the starting materials or building blocks to prepare biologically active pseudooligosaccharides. These attempts involving an advantageous utilization of the internal glycosidic linkages of the starting oligosaccharides were fulfilled on the basis of the methodology developed for their regioselective protection. All chiral carbocyclic constituents of the target compounds were prepared by applying the Ferriers carbocyclization reaction to the corresponding carbohydrate precursors.
社団法人有機合成化学協会の論文