ケイ素原子の特性を利用する環状付加反応
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The cycloaddition containing a desilylation process is one of the recently progressive area in the chemistry of organosilicon compounds. Especially, the 1, 3- cycloadditions via azomethine ylides derived from trimethylsilylmethylamine derivatives have been developed. In this article authors explain these 1, 3-cycloadditions via azomethine ylides, the thiocarbonyl ylide or trimethylenemethane-Pd complex and 1, 4-cycloaddition, leading to syntheses of useful heterocycles and naturally occurring compounds.
- 社団法人 有機合成化学協会の論文
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