金属クラスターおよび混合金属錯体を用いた新しい有機合成反応

概要

論文の詳細を見る
In homogeneous reactions catalyzed by transition metal complexes, the active species are in general mononuclear transition metal complexes and their catalytic activities are controlled by an appropriate choice of metals and ligands, especially phosphine ligands. Recently, homogeneous multimetallic catalysis has been receiving much attention because of the potential for the different metals cooperating during chemical transformations. It is expected that this cooperativity aids in the design of new, more active and selective catalysts and new types of reactions which are inaccessible through monometallic systems. Reviewed here are activation of substrates on metal clusters and various types of reactions catalyzed by metal clusters and mixed metal complexes.
社団法人有機合成化学協会の論文