新規環変換反応と天然物合成への応用

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概要

• 論文の詳細を見る

• Ring transformation reaction seems to be one of the important strategies in synthetic chemistry, because it enables otherwise synthetically difficult targets to be accessible by ring transformation from other, readily prepared ring systems. Recently, a novel ring transformation based on aldol condensation followed by acetalization and subsequent Grob fragmentation has been developed by our group. This ring transformation using BF<SUB>3</SUB> etherate/diol such as ethylene glycol seems to be widely applied for the synthesis. In this review, several reaction types of this ring transformation and its application to the synthesis of natural products having the unique skeleton are described.

• 社団法人 有機合成化学協会の論文

著者

• 酒井 浄

  九州大学薬学部

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