新しい有機合成 : 酸・塩基複合反応剤の知見と展望

概要

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Synthetically useful reactions mediated by reagents containing aluminum as a key atom are disclosed. The reagents perform combined acid-base attack on substrates with less activation energies. The aluminum Lewis acid center serves to bind the substrate and subsequently the base directly attached to aluminum is excited by the coordination and attacks the substrate in the following rate-and product-determining step. Supports of this idea as well as extensions are described.
社団法人有機合成化学協会の論文