金属錯体を用いるアセチレン誘導体の合成

概要

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Acetylenic compounds are valuable intermediates in organic syntheses. Application of organometallic complexes as a reagent or catalyst has developed extensively a variety of new methods of formation and introduction of an acetylenic group into organic structures.<BR>In this article, synthetic methods of acetylene derivatives using organometallic complexes are reviewed according to the following classification based on the type of reactions : 1) substitution reaction 2) addition reaction 3) elimination reaction 4) metathesis and reaction of carbyne metal complexes and 5) use of protecting groups.
社団法人有機合成化学協会の論文