The Reactions of Amino-s-triazines with Aromatic Amines. IV:The Replacements of Hydroxyl groups in N-phenylated Ammeline and Ammelide derivatives by Chlorine atoms.

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概要

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• N, N'-Diphenylammeline and N-phenylammeline, respectively, was refluxed for 1 hr. with phosphorus oxychloride for substitution of hydroxyl group in these compounds with chlorine and to give 2, 4-dianilino-6-chloro-s-triazine and 2-anilino-4, 6-dichloro-s-triazine with 13% and 71% yield, respectively. Triethylamine was effective as the catalyst and their yields were increased to 27% and 84%, respectively. Three kinds of monochloro-s-triazine type reactive dyes were synthesized using 2-anilino-4, 6-dichloro-s-triazine as the raw material.

• 社団法人 有機合成化学協会の論文

著者

• 本田 格

  福井大学工学部

• 笹木 洋佑

  福井大学工学部繊維染料学科

• 北川 修一

  福井大学工学部繊維染料学科

• 斉藤 聰

  福井大学工学部繊維染料学科

関連論文

• 1-クロル-2, 4-ジニトロアントラキノンについて
• ポリ-s-トリアジノヒドラジドの合成
• 2, 4-ジアミノ-6-メチル (またはフェニル) -S-トリアジンのヒドラジノ化
• アリールメラミン類の合成-1-
• The Reactions of Amino-s-triazines with Aromatic Amines. IV:The Replacements of Hydroxyl groups in N-phenylated Ammeline and Ammelide derivatives by Chlorine atoms.
• The Reactions of Amino-s-triazines with Aromatic Amines. II:The Reactions of Ammeline with Aromatic Amine Hydrochlorides

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