フッ素系潤滑油の耐塩化アルミニウム性

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概要

• 論文の詳細を見る

• The fluoro compounds for lubricants, such as hexakis (1, 1, 5-trihydroperfluoropentyloxy) cyclotriphosphazene (I) and perfluoropolyether (II), were examined comparatively concerning their chemical stabilities toward AlCl<SUB>3</SUB> at various temperatures. (I) was found to be an excellent lubricant as its decomposition occurred little and only a small amounts of phosgene evolved by heating in the presence of AlCl<SUB>3</SUB>. While (I) gave only small amounts of chlorine-containing compounds above 80°C in the presence of AlCl<SUB>3</SUB> (50%), (II) decomposed considerably, producing the chloro compounds with low molecular weight by the breakdown of main chain. At the reaction temperatures of 60-120°C, (I) were recovered more than 95% by the 1, 1, 2-trichlorotrifluoroethane (F-113) extraction. (II) recovered by the F-113 extraction decreased from 100% (23°C) to 41% (120°C) with the increase of reaction temperature. The amounts of phosgene evolved in the reaction of (I) and (II) with AlCl<SUB>3</SUB> were 0.0099 and 20.7 g/l at 100°C, respectively.

• 日本真空協会の論文

著者

• 村松 広重

  名古屋工業技術試験所

• 多田 祐二

  大塚化学株式会社

関連論文

• 燃焼法による有機化合物中のフッ素の定量
• フッ素系潤滑油の耐塩化アルミニウム性
• 含フッ素アセチレン類の合成と反応
• 含フッ素オレフインの反応
• 赤外線吸収スペクトルによるChlorobenzotrifluorideの異性体の定量

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