An Application of Thin-Layer Chromatography to Radiochemical Inspection of Iodide-<SUP>131</SUP>I and Sulfite- <SUP>35</SUP>S
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概要
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Thin-layer chromatography was applied to radiochemical purity determination of sulfites (<SUP>35</SUP>SO<SUP>2-</SUP><SUB>3</SUB>) and iodides (<SUP>131</SUP>I<SUP>-</SUP>), in which the samples were chromatographed on silica gel sheet with acetone-water mixture as solvent. Prior to actual application, certain compounds of S and I contained as impurities in the <SUP>35</SUP>SO<SUP>2-</SUP><SUB>3</SUB> and <SUP>131</SUP>I<SUP>-</SUP> were chromatograph-ically separated. The <I>R<SUB>f</SUB></I> values were determined as function of the concentration of the acetone solvent and of the concentration of the species in the sample solutions.<BR>Acetone was found to be a very effective solvent, only requiring the ratio of mixture with water to be changed to yield the <I>R<SUB>f</SUB></I> value of any compound, thus permitting the selection of a wide variety of solvent composition according to the combination of compounds to be developed. The solvent composition also influenced the developing time, which furnished another criterion in selecting the solvent composition. The <I>R<SUB>f</SUB></I> value was also greatly affected by the concentration of the species to be developed. Species that readily oxidized during chromatography-such as SO<SUP>2-</SUP><SUB>3</SUB>-tended to yield erroneous results.<BR>The thin-layer chromatographic technique studied in this work should be successfully applicable to the mutual separation of I<SUP>-</SUP>, I0<SUP>-</SUP><SUB>3</SUB> and I2, and SO<SUP>2-</SUP><SUB>3</SUB> and SO<SUP>2-</SUP><SUB>4</SUB>; it can be con-sidered a very promising alternative to paper-chromatography or electrophoresis, as standard method for the identification and purity inspection of radioactive products.
- 一般社団法人 日本原子力学会の論文
著者
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TANASE Masakazu
Japan Atomic Energy Research Institute
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Amano Hiroshi
Japan Atomic Energy Research Institute
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SHIKATA Eiji
Japan Atomic Energy Research Institute
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