Linear sweep voltammetry of nickel in molten LiF-NaF-KF eutectic.
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概要
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The linear sweep voltammetric study of Ni in molten LiF-NaF-KF eutectic was carried out at temperatures between 470 and 540°C by using an indicator electrode made of Pt bead. The observed reduction wave for Ni(II) was considered due to the reversible two-electron reduction, Ni(II)→ Ni(0). Nickel (II) can be determined in molten LiF-NaF-KF eutectic with the detection limit of 4 × 10<SUP>-4</SUP> mol/dm<SUP>3</SUP>. The diffusion coefficient of Ni(II) was found to be 5 × 10<SUP>-6</SUP> cm<SUP>2</SUP> Is at 500°C and its activation energy, (5.86 ± 1.67) × 10<SUP>-4</SUP> J/mol.
- 一般社団法人 日本原子力学会の論文
著者
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Inoue Yasushi
Department of Applied Physics, Osaka University
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TAGO Itaru
Department of Nuclear Engineering, Faculty of Engineering,Tohoku University
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TANAKA Koichi
Department of Anatomy and Cell Biology, Hyogo College of Medicine, 1–1 Mukogawa-cho, Nishinomiya, Hyogo 663–8501, Japan
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TANAKA Koichi
Department of Nuclear Engineering, Faculty of Engineering,Tohoku University
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INOUE Yasushi
Department of Nuclear Engineering, Faculty of Engineering,Tohoku University
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