Bi0.7Pb0.3SrCaCu1.8Oyの超電導特性 (酸化物系超伝導物質と材料) -- (昭和63年度秋季大会講演特集)

概要

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Superconductors(Tc=110K) have been synthesized in the process of researching fundamental conditions of preparation with starting composition of Bi0.7Pb0.3SrCaCu1.8Oy. The measurements and analysis such as electrical resistivity, X-ray diffraction, DTA, SEM and micro-Raman scattering have led to the conclusion: 1)the sintering condition of 830°C, 244 hours produces superconductor of Tc=110K, 2)this system shows an abnormal behavior in electrical resistivity near 145K, 3)X-ray diffraction analysis suggests that with increasing in sintering period of time, high-Tc phase increases in its ratio to low-Tc phase, 4)DTA result indicates that the best sintering is realized at the temperature at which the possible peritectic reaction may begin.
社団法人粉体粉末冶金協会の論文