Equation of state based on a group contribution model applicable to vapor and liquid phases and its application to n-alkane systems.
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概要
- 論文の詳細を見る
An equation of state is derived from a group contribution model which takes into account the effect of local molecular distribution on potential energy in terms of the non-random two-liquid (NRTL) model. Model parameters for methyl and methylene groups are determined from the data reduction of saturated properties of n-alkanes. It is shown that the equation of state correlates well the saturated properties of "-alkanes and successfully predicts the vapor-liquid equilibria of n-alkane binary mixtures.
- 公益社団法人 化学工学会の論文
著者
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Takishima Shigeki
Department Of Chemical Engineering Graduate School Of Engineering Hiroshima University
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Saito Shozaburo
Department of Biochemistry & Engineering, Tohoku University
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