ゆらぎと回折実験 : ―回折学と熱力学の接点―
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概要
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In order to reveal the mixing state of two-component liquids, a description of “fluctuation” is presented on behalf of the strucutre description by radial distribution functions. The concentration fluctuation and the Kirkwood-Buff parameters are the good parameters to investigate the mixing state. These parameters are obtained by small-angle X-ray scattering experiments. The theoritical base of the parameters is reviewed. As an example of the analysis of the mixing state, the small-angle X-ray scattering studies for ethyl alcohol-water, iso-propyl alcohol-water, n-propyl alcohol-water and tert-butyl alcohol-water are presented.
- 日本結晶学会の論文