CHEMICAL REACTION OF CARBON MONOXIDE WITH COPPER(I)-TETRACHLOROALUMINATE(III)-AROMATIC HYDROCARBON SOLUTIONS-EQUILIBRIUM AND KINETICS-

スポンサーリンク

概要

• 論文の詳細を見る

• Chemical reactions of CO gas with copper(I)-tetrachloroaluminate(III)-aromatic hydrocarbon solutions, namely COSORB solutions, were investigated from the viewpoint of equilibrium and kinetics. The equilibrium and the non-equilibrium amounts of CO dissolved into COSORB solutions were measured by using a batchwise gas-liquid contactor. Equilibrium properties such as CO gas solubility constants or CO-complex stability constants for various solvent solutions were determined from the experimental data with the aid of the optimization technique. The solubility of CO decreased with temperature as well as with concentration of CuAlCl4. The stability constants were influenced by the π-electron releasing ability of the aromatic hydrocarbon molecule. A rational reaction mechanism is proposed to explain the non-equilibrium rate data obtained experimentally. The reaction followed a unimolecular substitution mechanism and was determined to be exothermic. The COcomplex stability constant calculated from the optimum rate constant was in good agreement with the results of the equilibrium experiments.

著者

• YONEMOTO Toshikuni

  Department of Biochemistry and Engineering, Tohoku University

• Sato Tsuneyuki

  Department of Biochemistry and Engineering, Tohoku University

• Kato Haruo

  Department Of Neurosurgery Nara Emergency And Critical Care Center

• TADAKI Teiriki

  Department of Biochemistry and Engineering Tohoku University

• YAMAMORI YOSHIYUKI

  Department of Chemical Engineering, Tohoku University

• TOYODA ITSUO

  Department of Chemical Engineering, Tohoku University

• KATO HARUO

  Department of Chemical Engineering, Tohoku University

• TADAKI TEIRIKI

  Department of Chemical Engineering, Tohoku University

関連論文

• SEPARATION OF AMINO ACIDS BY RECYCLING FREE-FLOW ELECTROPHORESIS
• Continuous-Flow Electrophoresis for Concentration of Protein
• Separation of Proteins by Continuous Isoelectric Focusing
• Numerical Simulation of a Continuous Flow Isoelectric Focusing for Concentration of Amino Acid
• Separation of Amino Acids by Continuous-Flow Electrophoresis
• Synthesis of Monodispersed Nano Size Titania Particles by Alkoxide Method in the Presence of Hydroxypropylcellulose
• Regional Cerebral Blood Flow After Status Epilepticus
• Hyperbranched Polymer through Initiator-Fragment Incorporation Radical Copolymerization of Divinyl Adipate with Allyl Acetate : Synthesis, Characterization, Dye Solubilization, Metal-Nanoparticle Stabilization, and Porous Film Formation
• Progressive Effect of Water on Prevention of β-Carotene Oxidation in Biphasic Oil-Water System with Addition of an Antioxidant, α-Tocopherol
• Kinetics of Solvent-Free C-Alkylation of Phenylacetonitrile Using Ultrasonic Irradiation
• Cultures of Nicotiana tabacum Cells Immobilized in Calcium Alginate Gel Beads Coated with Cell-Free Gel Film
• MODELING OF IONIC TRANSPORT IN NEUTRALIZATION DIALYTIC DEIONIZATION
• Complete Separation of Ternary Mixture of Amino Acids Using Continuous Rotating Annular Chromatography with Partial Recycling of Effluent
• Simultaneous Isolation and Concentration of Target Solute from Multicomponent Mixture Using Continuous Rotating Annular Chromatograph with Double-Stage Partial Recycling of Effluent
• Kinetic Analysis for Oxidation of Oleic Acid
• Variational Theory for Two-Impurity Anderson Model : Condensed Matter and Statistical Physics
• Modeling of the Formation Kinetics of Polyurea Microcapsules with Size Distribution by Interfacial Polycondensation
• CHEMICAL REACTION OF CARBON MONOXIDE WITH COPPER(I)-TETRACHLOROALUMINATE(III)-AROMATIC HYDROCARBON SOLUTIONS-EQUILIBRIUM AND KINETICS-
• Ionic transport in a continuous Donnan dialyzer with two parallel-plate channels.
• Ionic Transport in a Continuous Donnan Dialyzer with a Parallel Plate Channel and an Agitated Tank
• Modified structural model for solid-consuming reaction. A case of slab-like tablet.:A CASE OF SLAB-LIKE TABLET
• Kinetics of carbon deposition on nickel metal by decomposition of carbon monoxide.
• Reaction characteristics of the horizontal Epitaxial reactor.
• Mathematical analysis of kinetics of solid-consuming reaction.
• Temperature distribution and reaction characteristics of the horizontal epitaxial reactor in high flow rate range.
• Sublimation mass transfer from a cylinder to the gas flowing laminarly in a parallel-plate duct.
• Reduction of nickel oxide pellet by a H2-CO mixture accompanied by carbon deposition.
• The reaction order of solid concentration for volume reaction model.
• Velocity profile and temperature distribution in the horizontal epitaxial reactor.
• Effect of oscillatory instability on stability of two-fluid layers.
• Solid concentration dependence of reaction rate for volume reaction model in fluid-solid reactions.
• P18. Ultrasonic degradation of phenol in water in the presence of Fe doped TiO_2(Poster Presentation)
• Properties of Protein Adsorption and Desorption of Alumina Ceramic Membrane.

もっと見る 閉じる

スポンサーリンク