Preparation and crystal structure of [enH2]0.5[Ho(HPO4)(SO4)(H2O)] (en; ethylenediamine)
スポンサーリンク
概要
- 論文の詳細を見る
Single crystals of an organically templated holmium hydrogen phosphate sulfate, [enH2]0.5[Ho(HPO4)(SO4)(H2O)] (en; ethylenediamine) were prepared by hydrothermal reaction and its crystal structure was determined by single crystal X-ray diffraction data. This compound crystallized in the monoclinic system, space group P21/a (No. 14) and the unit cell parameters are a = 12.938(5), b = 6.834(3), c = 9.100(2) Å, and β = 88.12(2)°. The crystal structure is similar to that of [enH2]0.5[Ce(HPO4)(SO4)(H2O)] which had a layered structure built up by Ce centered polyhedra and HPO4 and SO4 tetrahedra, and the diprotonated ethylenediamine cations were located in the interlayer. For other rare earth elements two types of compounds were obtained under hydrothermal conditions. The compounds of R = La, Pr, Nd, Sm and Eu are isostructural with [enH2]0.5[Ce(HPO4)(SO4)(H2O)] and those of Gd, Tb, Dy, Er and Yb with [enH2]0.5[Ho(HPO4)(SO4)(H2O)]. The unit cell volumes of these compounds decrease by lanthanide contraction. The compounds of R except La, Sm and Eu exhibited the Curie-Weiss paramagnetic behavior.
- 公益社団法人 日本セラミックス協会の論文
著者
-
Kumada Nobuhiro
Department of Research Interdisciplinary Graduate School of Medicine and Engineering, University of
-
Yonesaki Yoshinori
Department of Research Interdisciplinary Graduate School of Medicine and Engineering, University of
-
TAKEI Takahiro
Department of Research Interdisciplinary Graduate School of Medicine and Engineering, University of
-
KINOMURA Nobukazu
Department of Research Interdisciplinary Graduate School of Medicine and Engineering, University of
-
YU Ranbo
Department of Physical Chemistry, University of Science & Technology Beijing
-
Miyagawa Kazuya
Department Of Toxicology Hoshi University School Of Pharmacy And Pharmaceutical Sciences
-
Miyagawa Kazuya
Department Of Applied Physics University Of Tokyo:crest-jst
-
Kumada N
Interdisciplinary Graduate School Of Medical And Engineering Univ. Of Yamanashi
-
Kumada Nobuhiro
Department Of Research Interdisciplinary Graduate School Of Medicine And Engineering University Of Y
-
Kumon Junichi
Department of Research Interdisciplinary Graduate School of Medicine and Engineering, University of
-
WANG Dan
Key Laboratory of Multi-Phase and Complex System, Institute of Process Engineering, Chinese Academy
-
Wang Dan
Key Lab. Of Multi-phase And Complex System Inst. Of Process Engineering Chinese Acad. Of Sciences
-
Kinomura Nobukazu
Dep. Of Res. Interdisciplinary Graduate School Of Medicine And Engineering Univ. Of Yamanashi
-
Takei Takahiro
Department Of Research Interdisciplinary Graduate School Of Medicine And Engineering
-
Kinomura Nobukazu
Department Of Research Interdisciplinary Graduate School Of Medicine And Engineering
-
Miyagawa Kazuya
Department Of Applied Mathematics Faculty Of Engineering Science Osaka University
-
Yu Ranbo
Department Of Physical Chemistry University Of Science & Technology
-
Kumada Nobuhiro
Department of Research Interdisciplinary Graduate School of Medicine and Engineering
-
KUMON Junichi
Department of Research Interdisciplinary Graduate School of Medicine and Engineering, University of Yamanashi
-
WANG Dan
Key Laboratory of Multi-Phase and Complex System, Institute of Process Engineering, Chinese Academy of Sciences
-
YU Ranbo
Department of Physical Chemistry, University of Science and Technology Beijing
-
YONESAKI Yoshinori
Department of Material Chemistry, Graduate School of Engineering, Kyoto University
関連論文
- Preparation and characterization of hollow magnetite spheres via a template-free route
- Low temperature synthesis of tetragonal BaTiO3 by using molten salt
- Piezoelectric anomalies at the ferroelastic phase transitions of lead-free tungsten bronze ferroelectrics
- A Novel Open-framework Cerium Sulfate Hydrate : Synthesis and Characterization
- Quark-Model Baryon-Baryon Interaction and Its Applications to Hypernuclei(Proceedings of the 18th Nishinomiya Yukawa Memorial Symposium)
- Preparation of cordierite from fibrous sepiolite
- Superconductuvity at 14.2K in Layered Organics under extreme Pressure
- An Inorganic-Organic Hybrid Possessing a Two-dimensional Ti-O Network and Surface Ethoxy Groups Prepared via a Reaction of Titanium Oxychloride with Lithium Ethoxide
- Preparation and crystal structure of [enH2]0.5[Ho(HPO4)(SO4)(H2O)] (en; ethylenediamine)
- Hydrothermal synthesis of Fe_3O_4 particles with various shapes
- Crystal structure of pseudobrookite-type Mg_5Nb_4O_ from 293 to 1117K
- Synthesis of hematite particles with various shapes by a simple hydrothermal reaction(Aqueous Solution Science for Ceramic Processing II)
- Hydrothermal synthesis of a new perovskite-type bismuth oxide : Ba_Bi_O_(OH)_
- Hydrothermal synthesis of a new double perovskite-type bismuthate, (Ba0.75K0.14H0.11)BiO3・nH2O
- Hydrothermal conversion of chrysotile to amorphous silica or brucite
- Sorption of divalent Fe, Co, Ni, and mixed-valent Fe into mesoporous silica grafted with an aminopropyl group, and their adsorption properties
- Preparation of Na_Bi_TiO_3 by hydrothermal reaction
- Anodic electrodeposition of redoxable film from manganese oxide nanosheet
- Hydrothermal synthesis of perovskite-type BiFeO_3
- 13-P-09 Preparation of Mesoporous Silica Conductive Polymer Composite and its Electrochemical Property
- 01-O-41 Crystallization of Zirconium Phosphates from Organic Medium with Hydrothermal Technique : Effects of Synthesis Conditions
- The first Organically Templated Layered Cerium Phosphate-Hydrogen Sulfate : [enH_2]_[Ce^(PO_4)(HSO_4)(OH_2)]
- A Novel Layered Zirconium Phosphate [NH_4]_2[Zr(OH)_3(PO_4)] Synthesized through Non-aqueous Route
- Non-aqueous Synthesis and Structure of a Novel Monodimensional Zirconium Phosphate : [NH_4]_3[Zr(OH)_2(PO_4)(HPO_4)]
- Current Status of Emergency Care for ST-Elevation Myocardial Infarction in an Urban Setting in Japan(Critical Care)
- PJ-867 Impact of the difference of first contact physicians on door-to-balloon time in ST-elevation myocardial infarction(Emergency care / CPR(05)(H),Poster Session(Japanese),The 72nd Annual Scientific Meeting of the Japanese Circulation Society)
- Neutral-Ionic Phase Transition in DMTTF-QCl_4 Investigated by ^Cl NQR(Condensed matter: electronic structure and electrical, magnetic, and optical properties)
- PE-395 The characteristics of the patients with ST-elevation myocardial infarction who achieved a guideline-recommeded door-to-balloon time of 90 minutes(Coronary revascularization, PCI(13)(IHD),Poster Session(English),The 72nd Annual Scientific Meeting o
- OE-394 The present status of emergency care for ST-elevation myocardial infarction in the urban area(Emergency care/CPR(01)(H),Oral Presentation(English),The 72nd Annual Scientific Meeting of the Japanese Circulation Society)
- Redundant Components in the 3α Faddeev Equation Using the 2α RGM Kernel
- Three-Cluster Equation Using the Two-Cluster RGM Kernel
- An Effective Route for Porous Ferrihydrite Preparation from Layered Double Hydroxide Precursors
- Preparation of a Porous Iron Oxyhydroxide from Layered Double Hydroxides Precursors(Layered Double Hydroxides and Anionic Clays,Proceedings of the 13^ International Clay Conference)
- Faddeev Calculation of d-a Scattering with Absorption Effects : Nuclear Physics
- Self-assembly of a Novel Manganiferous Coordination Polymer with Mixed Ligands
- NMR Evidence for Antiferromagnetic Transition in the Single-Component Molecular Conductor, [Au(tmdt)_2] at 110 K(Condensed matter : electronics structure and electrical, magnetic, and optical properties)
- Adsorption of Cl^- Ion with Pyrolysis Products of Yttrium Oxynitrate Hydrate, Y_2(OH)_(NO_3)_x・nH_2O
- In Situ Ligand Synthesis for a Novel 1-D Mn Coordination Polymer
- Spin Liquid in a Spin-Frustrated Organic Mott Insulator(Frustrated Systems, Field-Induced Phase Transitions and Dynamics in Quantum Spin Systems)
- Synthesis of LiCoO2 via a facile hydrothermal-assisted route
- Preparation and crystal structure of two types of zirconium phosphates by hydrothermal reaction
- Second-Harmonic Generation in Thermally/Electrically Poled Transparent BaTiO_3 Thin Films Prepared by Dip-Coating Method
- Synthesis of hematite particles with various shapes by a simple hydrothermal reaction
- Chronic treatment with diphenylarsinic acid (DPAA) affects central nerves system(Proceedings of the 32nd Annual Meeting)
- Structural Transformation of Hexagonal (0001)BaTiO3 Ceramics to Tetragonal (111)BaTiO3 Ceramics
- Changes in Central Dopaminergic Systems with the Expression of Shh or GDNF in Mice Perinatally Exposed to Bisphenol-A
- Hydrothermal synthesis of NaNbO3—morphology change by starting compounds—
- Charge-Lattice-Coupled Quantum Fluctuations in DMTTF–2,6-QBr2Cl2
- 13C NMR Study on Zero-Gap State in the Organic Conductor $\theta$-(BEDT-TTF)2I3 under Pressure
- Hydrothermal Synthesis of a New Double Perovskite-Type Bismuthate, (Ba0.75K0.14H0.11)BiO3$\cdot$$n$H2O
- Quark-Model Baryon-Baryon Interaction and Its Applications to Hypernuclei(Proceedings of the 18th Nishinomiya Yukawa Memorial Symposium)
- 26pDJ-12 Study of the interplay between charge ordered and Dirac fermions system of α-(BEDT-TTF)_2I_3 with transport properties investigation under ambient to intermediate pressures