Calculating the Critical Relative Humidity from the Solubility of Electrolyte According to Extended Non-random Two Liquid Model

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概要

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• According to thermodynamic principle, the critical relative humidity of electrolytes is closely related to their solubility. The authors explored the relationship theoretically and calculated the critical relative humidity of 21 electrolytes in the light of Raoults law, modified Debye–Hückel model and extended non-random two liquid (NRTL) model from their solubility. The results indicate that the critical relative humidity values calculated by Raoults law can not accord with the reported ones and there is a systematic error in high concentration range; the values calculated by modified Debye–Hückel model still can not accord with the reported ones well although without systematic error; and the values calculated by extended NRTL are comparable to the reported ones.

• 公益社団法人　日本薬学会の論文

著者

• Wang Yingli

  Key Laboratory of Drug Targeting, West China School of Pharmacy, Sichuan University

• Zhan Xiancheng

  Key Laboratory of Drug Targeting, West China School of Pharmacy, Sichuan University

• Xiang Chaoqun

  Key Laboratory of Drug Targeting, West China School of Pharmacy, Sichuan University

• Chen Jia

  Key Laboratory of Drug Targeting, West China School of Pharmacy, Sichuan University

• Cao Lan

  Key Laboratory of Drug Targeting, West China School of Pharmacy, Sichuan University

• Hou Manzhou

  Key Laboratory of Drug Targeting, West China School of Pharmacy, Sichuan University

• Li Linli

  Key Laboratory of Drug Targeting, West China School of Pharmacy, Sichuan University

• Li Chengrong

  Key Laboratory of Drug Targeting, West China School of Pharmacy, Sichuan University

関連論文

• Calculating the Critical Relative Humidity from the Solubility of Electrolyte According to Extended Non-random Two Liquid Model
• Compressed Oxygen in Drug Stability Experiments

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