Self-Regeneration Pd-Perovskite Anode for SOFC
スポンサーリンク
概要
- 論文の詳細を見る
A Pd doped perovskite La0.85Sr0.15Cr0.9Ni0.05Pd0.05O3 (LSCNP) was investigated as a candidate for a metal-free anode material of solid oxide fuel cell in comparison with La0.85Sr0.15Cr0.9Ni0.1O3 (LSCN). The performance of anodes of LSCNP and LSCN with and without mixing Sm doped Ceria (SDC) was measured using H2 and dry-CH4 as fuel. The maximum current density of the cell in H2 increased approximately twofold by the doping of Pd for the anode with or without SDC. The rate of the anodic reaction in H2 was enhanced mainly by the catalytic activity of LSCNP and additionally by SDC. When dry-CH4 was used as the fuel, the cell with LSCNP-SDC anode was the only cell which was able to perform power generation. Both the doping of Pd to the perovskite and the mixing of SDC contributed to the ability to operate SOFC in dry CH4. The anode reaction did not occur when SDC was not in the anode, indicating that the supply of oxide ion was the rate determining step. Pd, which is considered to deposit from LSCNP in reducing atmosphere, seemed to be the reaction site of the electrochemical methane oxidation since the reaction rate was low for LSCN-SDC. Although slight indication of carbon deposition was observed, Pd doped perovskite would be a good candidate for metal-free SOFC anode.
著者
-
Yamada Koichi
The University Of Tokyo
-
Fukunaga Hiroshi
Department Of Applied Chemistry Waseda University
-
Arai Chikao
Depart. Of Clinical Functional Physiology Faculty Of Medicine Toho Univ.
-
Takatsuka Toru
Department of Fine Materials Engineering, Shinshu University
-
Numazawa Yoshimi
Department of Fine Materials Engineering, Shinshu University
-
Fueoka Akinori
Department of Fine Materials Engineering, Shinshu University
-
Fukunaga Hiroshi
Department of Fine Materials Engineering, Shinshu University
関連論文
- E. camaldulensis Optimal Planting Density in Desert Western Australia in View of Its Photosynthetic Properties
- Surface Conductivity in Methyl-monolayer/Si Heterojunction Structure in the Presence of Water
- PE-206 Multi-center Experience and Favorable Long-term Prognosis of Cypher DES in Treating Small Coronary Arteries (≤3.0mm diameter) Compared with Bx Velocity Stents(Coronary revascularization, PCI-12 (IHD) PE35,Poster Session (English),The 70th Annive
- OE-224 What Should We Do for Restenosis after Cypher DES Deployment : Another Cypher, CABG, or Medical Treatment?(Coronary revascularization, PCI-2 (IHD) OE38,Oral Presentation (English),The 70th Anniversary Annual Scientific Meeting of the Japanese Circu
- OE-188 Clinical Impact and Favorable Long-Term Prognosis of Cypher DES Use for In-Stent Restenosis : A Multi-Center Analysis(Coronary revascularization, PCI-1 (IHD) OE32,Oral Presentation (English),The 70th Anniversary Annual Scientific Meeting of the Jap
- Reduction of Restenosis of Proximal Calcified LAD Lesions by Rotablator-Cypher DES Compared to Rotablator-Bare Metal Stents. A Triple-Center Analysi (Coronary Revascularization, PTCA/Stent/DCA/Rotablator/New Device 12 (IHD), The 69th Annual Scientific Mee
- Significant Effect to Reduce Restenosis by Cypher DES Compared to Velocity Stents After Rotablator in Hemodialysis Patients. A Multi-Center Experience(Coronary Revascularization, PTCA/Stent/DCA/Rotablator/New Device 17 (IHD), The 69th Annual Scientific Me
- Review of Safety and Effectiveness of Ticlopidine Use for Cypher Drug Eluting Stents(DES) : A Multi-Center Analysis in Japan(Coronary Revascularization, PTCA/Stent/DCA/Rotablator/New Device 10 (IHD), The 69th Annual Scientific Meeting of the Japanese Circ
- Electrochemical Behavior of Methyl- and Butyl- Terminated Si(111) in Aqueous Solution
- La0.85Sr0.15Cr0.9Ni0.05Pd0.05O3 Perovskite Anode for SOFC
- Self-Regeneration Pd-Perovskite Anode for SOFC
- Improvement Effect of Semi-Arid Land Afforestation on Soil Environment
- Baseline and Stand Structural Attributes Changes in Arid Woodland Vegetation
- Relation between Growth of Planted Trees and Soil Chemical Properties in Afforestation Sites of Semi-arid Land, WA
- Basic data of research project on large scale afforestation of arid land for carbon fixation near Leonora in Western Australia (小特集 沙漠工学分科会)
- Effects of Calcined Bauxite as a Water-holding Material and a Way of Mixing it with Soil on Tree Growth
- Water Use Efficiency of Trees in Arid Lands : Plasticity to Water Conditions
- Development of Tree Growth Simulator Based on a Process Model of Photosynthesis for Eucalyptus Camaldulensis in Arid Land
- Biomass Growth Estimation of an Afforestation Site and Natural Forests in an Arid Land of Western Australia
- A Modeling Methodology of Large Scale Water Balance and Salt Accumulation for Afforestation in Arid Land
- Effect of temperature and light on germination of 12 afforested trees in South Western Australia
- Death of Trees in the Wheat Belt in Western Australia : Identification of the Causes by Chemical Analysis of Soil
- Development of a Model for Large Scale Water Balance in Arid Land
- Establishment of the Method to Estimate of Water Requirement Per Unit Carbon Fixation of a Tree in Arid Land
- Development of Integrated Simulator of Water Transport and Plant Growth as an Evaluation Tool of Arid Land Afforestation for CO_2 Fixation
- Comparative Analysis between Biomass and Topographic Features in an Arid Land, Western Australia
- Restructuring and Afforestation of Hardpan Area to Sequester Carbon
- Possibility of Large Scale Afforestation in Arid Lands as a Measure against Increases in CO2 Concentration (Proceedings of the International Conference on Desert Technology 4) -- (New Technologies for the Rehabilitation of Arid Areas)
- STUDIES ON THE MECHANISM OF CORONARY ATHEROSCLEROSIS OCCURRENCE : THE HISTOCHEMICAL DETERMINATION OF SMOOTH MUSCLE FIBER AND CONNECTIVE TISSUE : Pathophysiology : 46th Annual Scientific Meeting, Japanese Circulation Society
- A STUDY ON THE EXPERIMENTAL CORONARY ARTERIOSCLEROSIS : THE HISTOCHEMICAL DETERMINATION OF THE MEDIAL SMOOTH MUSCLE FIBER AND THE CONNECTIVE TISSUE : Pathophysiology : 46th Annual Scientific Meeting, Japanese Circulation Society
- The Photocurrent of Dye-Sensitized Solar Cells Enhanced by the Surface Plasmon Resonance
- PRACTICAL EVALUATION OF CARDIAC RESERVE BY ADDITIONAL LOADING OF EXERCISE : VECTOR ANALYSIS REFERRING TO PRINCIPAL COMPONENTS OF VARIOUS HEMODYNAMIC FACTORS : Exercise Test (II) : FREE COMMUNICATIONS (VI) : PROCEEDINGS OF THE 49th ANNUAL SCIENTIFIC MEETIN
- Drying of Porous Solid Particles in Various-Shaped Spouted Bed with a Draft-Tube
- Factors Affecting Distribution of Nutrient in Tree Organs of Eucalyptus camaldulensis in Arid Lands of Western Australia
- Soil Mites in Re-afforested, Semi-arid Landscapes in Western Australia
- Effect of Diltiazem on Coronary Hemodynamics and Its Clinical Significance
- Growth of Trees Planted for Rehabilitation of a Saline Area of the Wheatbelt in Western Australia
- Arterial. Disturbance in SHRSP as Observed by Comparison among Aorta, Coronary Artery and Cerebral Artery
- A Study on Coronary Damage in SHRSP:The Determination of Medial Tissue Collagen
- The damages of aorta and coronary artery in SHRSP:synthetic estimation of smooth muscle cell and connective tissues contents by principal component analysis
- The damage of aorta in SHRSP:the estimation of smooth muscle cell and connective tissues contents
- Aortic Function (PWV) and Change of Vascular Wall Components:Comparison between WKY, SHRSR and SHRSP
- A Study on Coronary Disorders in SHRSP:The Determination of Medial Tissue Elastin
- The transition of the medial acid mucopolysaccharides value in the thoracic aorta of SHRSP with aging
- Day-Old Characteristics of Cerebroarterial Disturbance in SHRSP Determination of cell and intercellular matrix
- Factors Affecting the Distribution of Nutrients in the Tree Organs of Eucalyptus camaldulensis in the Arid Lands of Western Australia
- The transition of the medial smooth muscle cell fiber in the thoracic aorta of SHRSP with aging
- The damage of coronary artery in SHRSP:the estimation of smooth muscle cell and connective tissues contents
- Determination of Aortic Medial Tissue Glycoprotein (GP) in Stroke-Prone Hypertensive Rats
- A Study on Coronary Damage in SHRSP:The Determination of Cell Nuclear in Smooth Muscle Cell
- The comparison of constructional property between aorta and coronary artery in SHRSP and WKY:synthetic estimation of smooth muscle cell and connective tissues contents by principal component analysis
- Cerebral Arterial Disorder in SHRSP:The Determination of Cells and Various Connective Tissues
- Architectual Disturbance of Arteria Cerebri in SHRSP:With special reference to the determination of its cell and various connective tissues
- Architectural Disturbance Characteristics of Rat's Aorta:Confrontation among SHRSP, Sclerotic Rabbit and Sclerotic Man
- A Study on Myocardial Damage in SHRSP:The Determination of Collagen in Myocardium