Divergent Synthesis of Lamellarin α 13-Sulfate, 20-Sulfate, and 13,20-Disulfate

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概要

• 論文の詳細を見る

• A divergent synthesis of three sulfate derivatives of lamellarin α, namely, lamellarin α 13-sulfate (2), 20-sulfate (1), and 13,20-disulfate (4) has been achieved via a common intermediate (6) in which 13-OH and 20-OH of the lamellarin core are differentially protected by MOM and benzyl groups, respectively. Compound (6) in turn was prepared using sequential Suzuki-Miyaura coupling of 3,4-dihydroxypyrrole bistriflate (7) as a key reaction.

• 2010-03-01

著者

• FUKUDA Tsutomu

  Division of Chemistry and Materials Science, Graduate School of Engineering, Nagasaki University

• Fukuda Tsutomu

  Division Of Chemistry And Materials Science Graduate School Of Engineering Nagasaki University

関連論文

• Divergent Synthesis of Lamellarin α 13-Sulfate, 20-Sulfate, and 13,20-Disulfate
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