Memory of Chirality in the Electrochemical Oxidation of N-o-Phenylbenzoylated Prolinols

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概要

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• Memory of chirality in electrochemical carbon-carbon bond cleavage of N-o-phenylbenzoylated (S)-prolinol derivatives was observed. Substituents of the α-position affected the ee of the products. The reaction of α,α-diarylated (S)-prolinol derivatives proceeded smoothly to afford optically active α-methoxylated pyrrolidine with up to 73% ee.

• The Japan Institute of Heterocyclic Chemistryの論文

著者

• Matsumura Yoshihiro

  Nagasaki Univ. Nagasaki Jpn

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• Memory of Chirality in the Electrochemical Oxidation of N-o-Phenylbenzoylated Prolinols
• Asymmetric Introduction of Nucleophiles to the 2-Position of Pyrrolidine Ring through N-Acylpyrrolidinium Ion

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