メキシコイトスギ培養細胞中で生産されるモノテルペン類

概要

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A novel monoterpene, (1S, 2S, 6S)-(+)-1,6-epoxy-4(8)-p-menthen2-01, was isolated from an elicitor-treated cell culture of Cupressus lusitanica (Mexican cypress). Ten known monoterpenes - limonene, myrcene, $ \beta $-ocimene, sabinene, terpinolene, 4-terpineol, $ \alpha $-terpineol, 4 (8) -p-menthen-l,2-diol, 4-hydroxyphellandric acid methylester and $ \beta $thujaplicin methylether - were also identified. Regioselective metabolisms of monoterpenes were observed in this culture.エリシターを作用させたメキシコイトスギ（Cuprsssas　lusitanica）培養細胞が生産するモノテルペンを同定した。既知のテルペン類、limonene, myrcene,$ \beta $－ocimene, sabinene, terpinolene, 4－terpineol$ \alpha $－terpineol, 4（8）-p-menthen-1,2－diol，4－hydrexyphllandric acid methylester，$ \beta $－thujaplicinmethyletherとともに未報告のモノテルペン、(1S，2S，6S)-(＋)-1，6－epoxy－4（8）-p-menthen-2-olが見いだされた。本培養細胞におけるテルペン類の代謝反応はレギオ選択的であった。
2004-08-00